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Data pro 2018/2019

Coordination Chemistry

Kredity 6
Rozsah 3 / 1 / 0
Examinace Zk
Jazyk výuky angličtina
Úroveň magisterský předmět
Garant Ing. Irena Hoskovcová, CSc.

Anotace

None

Sylabus

1. History of coordination chemistry
2. Crystal Field Theory, Ligand Field Theory.
3. Molecular orbitals in coordination compounds.
4. Coordination polyhedra, fluxionality. Continuous symmetry concept..
5. Isomerism. Description ad determination of the absolute configuration.
6. Stability of coordination compounds, mechanisms of ligand substitution.
7. Ligands and their classification: nature of donor atoms, bonding possibilities. Chelates.
8. Metal - ligand interaction from the Lewis acid-base theory’s point of view.
9. Allyl complexes, metallocenes, cyclic ligands, template effect.
10. Polynuclear complexes, clusters.
11. Changes of ligand properties and reactivity after coordination to a metal centre.
12. Spectroscopy of coordination compounds. Photochemical reactions.
13. Magnetic properties of coordination compounds. Molecular magnets.
14. Electron transfer mechanisms.

Literatura

None

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