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Data pro 2019/2020

State Behaviour and Thermodynamic Properties of Fluids

Kredity 7
Rozsah 3 / 2 / 0
Examinace Zk
Jazyk výuky angličtina
Úroveň []
Garant prof. Ing. Květoslav Růžička, CSc.
Elektronické materiály dostupné v e-learningu VŠCHT

Anotace

The course deals with the state behavior and thermodynamic properties of homogeneous fluid systems. Special attention is devoted to the description of state behavior of multicomponent systems, as well as to the calculation of thermodynamic properties of such systems. Calculation and usage of partial molar quantities is also covered. Finally, phase equilibria calculations by means of EOS (equations of state) are discussed.

Sylabus

1. PVT behaviour of real fluids.
2. Introduction to intermolecular forces, Lennard - Jones potential.
3. Virial equation of state.
4. Equations of state for real fluids.
5. Theorem of corresponding states and its application.
6. State bahaviour of real mixtures.
7. Thermodynamic properties of ideal gas.
8. Departure function of real gas.
9. Termodynamic properties of real fluids.
10. Calculation of heat and work at different conditions.
11. Partial molar properties.
12. Fugacity and chemical potential.
13. Phase equilibria of single component systems.
14. Vapor pressures and related properties (experimental and estimation methods).

Literatura

R: Novák J.P., Růžička K., Fulem M., Calculation of Thermodynamic Functions from Volumetric Properties, doi:10.1039/9781782627043-00476 (Chapter 17 in Volume Properties: Liquids, Solutions and Vapours, Letcher T., Wilhelm E., 2015, Royal Society of Chemistry, London, ISBN: 978-1-84973-899-6)

R: Sandler, S.I., Chemical, biochemical, and engineering thermodynamics. 2006, Hoboken, N.J.: John Wiley. ISBN 978-0-471-66174-0

A: Michelsen, M.L. and J.M. Mollerup, Thermodynamic models : fundamentals & computational aspects. 2007, Holte, Denmark: Tie-Line Publications. ISBN 87-989961-3-4

A: Riazi, M.R., Characterization and properties of petroleum fractions. 2005, West Conshohocken, PA: ASTM International. ISBN 407.0-8031-3361-8

A: Span, R., Multiparameter equations of state : an accurate source of thermodynamic property data. 2000, Berlin: Springer. ISBN 3-540-67311-3

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